Victor Bardakov

Victor Bardakov

PhD student (2020-2024)
Saint Petersburg University
A Precise Synthetic Toolbox: H-Bond-Assisted Quadruple Reactivity of o-Dimethylaminoaryloximes featured image

A Precise Synthetic Toolbox: H-Bond-Assisted Quadruple Reactivity of o-Dimethylaminoaryloximes

It has been shown that azomethines, hydrazones, and oximes derived from 2(7)-carbonyl derivatives of 1,8-bis(dimethylamino)naphthalene can undergo acid-catalyzed heterocyclization …

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Dr. Semyon Tsybulin
«Buttressing Effect» in the Halogen-Lithium Exchange in ortho-Bromo-N,N-dimethylanilines and Related Naphthalenes featured image

«Buttressing Effect» in the Halogen-Lithium Exchange in ortho-Bromo-N,N-dimethylanilines and Related Naphthalenes

Non-covalent interactions such as coordination of an organolithium reagent by a directing group and steric repulsion of substituents strongly affect the halogen-lithium exchange …

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Stepan Meshalkin
Organoboron Derivatives of 1,8-Bis(dimethylamino)naphthalene: Synthesis, Structure, Stability, and Reactivity featured image

Organoboron Derivatives of 1,8-Bis(dimethylamino)naphthalene: Synthesis, Structure, Stability, and Reactivity

A series of ortho-, meta-, and para-boronic acids and their pinacol esters of 1,8-bis(dimethylamino)naphthalene (DMAN), including the very first …

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Victor Bardakov
Sterically facilitated meta-lithiation of arenes, containing electron donating groups featured image

Sterically facilitated meta-lithiation of arenes, containing electron donating groups

The influence of the bulky trimethylsilyl substituent on the selectivity of metallation of dimethylaniline, anisole and 1-dimethylaminonaphthalene is studied. The neighboring SiMe3 …

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Dr. Alexander Antonov
Laying the way to meta-functionalization of naphthalene proton sponge via the use of Schlosser's superbase featured image

Laying the way to meta-functionalization of naphthalene proton sponge via the use of Schlosser's superbase

Lithiation of 1,8-bis(dimethylamino)naphthalene (DMAN) with Schlosser's superbase (n-BuLi–t-BuOK) in the presence of TMEDA in hexane was examined. It has been shown that, compared …

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Dr. Alexander Antonov