ACOC6 in Antalya (Feb 9–11, 2026)
Dr. Antonov attended the 6th Anatolian Conference on Organic Chemistry in Antalya, Türkiye — a great few days of talks, new ideas, and meeting old friends and making new ones.
Hydrogen-Bond-Assisted Configurational Diversity of Benzamidines: Experimental and Theoretical Study
Configurational diversity and mechanisms of prototropic tautomerism of 15 N,N’-diarylbenzamidines as potential building blocks in H-bonded polymeric materials are investigated. …
edem-r.-chakalov
A data-driven and quantum chemistry-anchored framework for modeling and classifying carbon–lithium bonding in organolithium aggregates
We present a quantum chemistry-based, data-driven framework for the automated classification of carbon–lithium bonding motifs in archetypal organolithium aggregates. Starting from …
Hydrogen-bond-assisted Chalcogen Transfer Between Phosphine Selenides and Arsine Oxides
The Brønsted acid catalysis is widely regarded as one of the most effective methods for activating inert substrates and enabling unique reactivity. In this work, we introduce the …
d.-v.-krutin
A Precise Synthetic Toolbox: H-Bond-Assisted Quadruple Reactivity of o-Dimethylaminoaryloximes
It has been shown that azomethines, hydrazones, and oximes derived from 2(7)-carbonyl derivatives of 1,8-bis(dimethylamino)naphthalene can undergo acid-catalyzed heterocyclization …
Flipping the Metalation of 4-Dimethylaminopyridine: Steric Repulsion versus London Dispersion Attraction
It has been shown that azomethines, hydrazones, and oximes derived from 2(7)-carbonyl derivatives of 1,8-bis(dimethylamino)naphthalene can undergo acid-catalyzed heterocyclization …
Phosphine Selenides: Versatile NMR Probes for Analyzing Hydrogen OH···Se and Halogen I···Se Bonds
Nuclear magnetic resonance (NMR) spectroscopy is a powerful tool for studying the structure and dynamics of various non-covalent interactions. However, often spectral parameters …
a.-s.-zakharov
![Transition-Metal-Free Synthesis of 2-Substituted Benzo[cd]Indoles via the Reaction of 1-Halo-8-lithionaphthalenes with Nitriles featured image](/publications/30/publications/30/featured_hu_ca823911a65865ad.webp)
Transition-Metal-Free Synthesis of 2-Substituted Benzo[cd]Indoles via the Reaction of 1-Halo-8-lithionaphthalenes with Nitriles
A simple and effective organolithium approach to the synthesis of 2-substituted benzo[cd]indoles from peri-dihalonaphthalenes and nitriles has been developed. The reaction proceeds …
Chiral Diselenophosphoric Acids for Ion Pair Catalysis: A Novel Approach to Enhance Both Proton Donating and Proton Accepting Properties
The activation of poorly reactive substrates via strong chiral acids is a central topic in asymmetric ion pair catalysis these days. Despite highly successful scaffolds such as …
j.-eder
NMR detection of the strained metallacycles in organolithiums: theoretical study
For the first time through quantum chemistry methods, the effective use of 1JCLi spin–spin coupling constants as descriptors for assessing the formation of strained metallacycles …
m.-v.-kaplanskiy